Systematic pH-specific synthesis and structure transformations in binary-ternary In(III) assemblies with hydroxycarboxylic DPOT and aliphatic-aromatic chelators

pH-Specific synthetic reactivity in In(III) systems bearing variable denticity aliphatic-aromatic chelators led to 1D-3D binary-ternary (di)trinuclear assemblies linked through chemical transformations. Their physicochemical perusal offers insight into structural-electronic factor interplays useful in the development of well-defined crystalline In(III) metal-organic photoactive materials.211