Article ID Journal Published Year Pages File Type
7751247 Inorganica Chimica Acta 2015 7 Pages PDF
Abstract
The hypercoordinated monoorganodibromides were synthesized by interaction of tribromides RSnBr3 with O-TMS derivatives of N,N-disubstituted amides. In solution behavior of bromides differs from the analogous chlorides, including equilibrium dimer/monomer adducts with DMSO. In the case of chlorides the equilibrium is shifted toward monomers. In solid state tin compounds are dimeric.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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