| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7751307 | Inorganica Chimica Acta | 2014 | 7 Pages |
Abstract
The [2+2] cycloaddition reactivity of an osmium silylyne compound 2, [Cpâ(iPr3P)(H)OsSi(Trip)][HB(C6F5)3], with PhCCPh or PCtBu was studied by density functional theory (DFT) computations. These two reactions appear to be under kinetic control due to complex interplay between steric effects and the bonding interactions between two reacting fragments.86
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Zhenggang Xu, Michael B. Hall,