| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7751317 | Inorganica Chimica Acta | 2014 | 6 Pages |
Abstract
New niobium and tantalum imido complexes supported by the bis-N,N-(2,6-dichlorophenyl)-β-diketiminate ligand (BDICl) are reported. (BDICl)M(NtBu)Cl2py (1: Nb, 2: Ta) were used as precursors for the formation of the dimethylated complexes (BDICl)M(NtBu)Me2 (3: M = Nb, 4: M = Ta). Tantalum dialkyl imido complexes (BDICl)Ta(NtBu)Bn2 (5) and (BDICl)Ta(NtBu)(CH2SiMe3)2 (6) were prepared and characterized by NMR spectroscopy.65
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Michael Nechayev, Benjamin M. Kriegel, Thomas L. Gianetti, Robert G. Bergman, John Arnold,