| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7751319 | Inorganica Chimica Acta | 2014 | 7 Pages |
Abstract
The two-coordinate compound Zn{Si(SiHMe2)3}2 spontaneously undergoes reductive elimination to produce (Me2HSi)3Si-Si(SiHMe2)3 and metallic zinc. The transient disilylzinc compound is stabilized by a N-heterocyclic carbene or chelating N-donor ligands. Upon reaction with the Lewis acid B(C6F5)3, the β-SiH groups undergo β-hydrogen abstraction to give the corresponding silylzinc hydridoborate compounds.128
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Nicole L. Lampland, Arkady Ellern, Aaron D. Sadow,