Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7751324 | Inorganica Chimica Acta | 2014 | 14 Pages |
Abstract
The electronic and molecular structures of the half-open ferrocene [(η5-Pdlâ²)Fe(η5-Cpâ³)] and its closed analogue [(η5-Cpâ²)Fe(η5-Cpâ³)] (Cpâ²Â = 1,3-(Me3C)2C5H3) were compared. Both complexes can be cleanly oxidized to give the half-open ferrocenium and closed ferrocenium, respectively; but they are low spin molecules with different electronic ground states. 119
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Matthias Reiners, Dirk Baabe, Peter Schweyen, Matthias Freytag, Peter G. Jones, Marc D. Walter,