Article ID Journal Published Year Pages File Type
7751324 Inorganica Chimica Acta 2014 14 Pages PDF
Abstract
The electronic and molecular structures of the half-open ferrocene [(η5-Pdl′)Fe(η5-Cp″)] and its closed analogue [(η5-Cp′)Fe(η5-Cp″)] (Cp′ = 1,3-(Me3C)2C5H3) were compared. Both complexes can be cleanly oxidized to give the half-open ferrocenium and closed ferrocenium, respectively; but they are low spin molecules with different electronic ground states. 119
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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