Article ID Journal Published Year Pages File Type
7751385 Inorganica Chimica Acta 2013 7 Pages PDF
Abstract
Ruthenium nitrosyl complex [Ru(η1-L1)(PPh3)2(NO)Cl2] (2) was synthesized and molecular structure of 2 was determined by X-ray crystallography. Complex 2 acted as novel nitric oxide (NO) donor under light and provided precursor complex [Ru(η2-L1)(PPh3)2Cl2] (1) after NO delivery. Complex 1 was found to be potential NO scavenger. Flipping of denticity of carboxylate ligand was observed during NO donation and scavenging.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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