| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7751652 | Inorganica Chimica Acta | 2013 | 6 Pages |
Abstract
⺠Reactions of rhenium-nitrosyl complexes with polyamine ligands have been examined. ⺠Rhenium(II)-nitrosyl complexes give an array of unstable products due to redox chemistry. ⺠Rhenium(I)-nitrosyl complex [ReBr2(NO)(NCMe)3] gives multiple products that are more stable. ⺠Products from reaction of [ReBr2(NO)(NCMe)3] with a pentadentate polyamine ligand are presented.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![The synthesis and characterization of rhenium nitrosyl complexes. The X-ray crystal structures of [ReBr2(NO)(NCMe)3], [Re(NO)(N5)](BPh4)2] and [ReBr2(NO)(NCMe){py-CH2-NHâ¼CH2CH2-N(CH2-py)2}]](/preview/png/7751652.png "First Page Preview: The synthesis and characterization of rhenium nitrosyl complexes. The X-ray crystal structures of [ReBr2(NO)(NCMe)3], [Re(NO)(N5)](BPh4)2] and [ReBr2(NO)(NCMe){py-CH2-NHâ¼CH2CH2-N(CH2-py)2}]")
Authors
Ashfaq Mahmood, Zeynep Akgun, Yijie Peng, Peter Müller, Yanfeng Jiang, Heinz Berke, Alun G. Jones, Terrence Nicholson,