| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7752166 | Inorganica Chimica Acta | 2012 | 6 Pages |
Abstract
⺠Ni2+ and Co2+ complexes transform zirconium oxo-carboxylate clusters into isostructural 2.6 nm {M6Zr24} macrocycles. ⺠Intra-cluster condensation results in new {Zr12O22} framework. ⺠Some Ni2+/Co2+ sites display rare eightfold coordination. ⺠Antiferromagnetic coupling between spin centers is efficiently mediated by zirconium oxide fragments.
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Chemistry
Inorganic Chemistry
Authors
Iurii L. Malaestean, Meliha Kutluca, Manfred Speldrich, Arkady Ellern, Paul Kögerler,