| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7752182 | Inorganica Chimica Acta | 2012 | 7 Pages |
Abstract
⺠A family of chloro-ethynylbenzene complexes containing [(cyclam)Co]3+ units are prepared via dehydrohalogenation routes. ⺠Co:ligand reactant ratios and concentration of exogenous base affect product nuclearity. ⺠Stepwise ligand substitution is demonstrated, offering control of complex nuclearity. ⺠Electrochemical characterization shows solution instability of reduced Co-ethynylbenzene complexes.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Wesley A. Hoffert, Md. Khayrul Kabir, Ethan A. Hill, Sara M. Mueller, Matthew P. Shores,