Article ID Journal Published Year Pages File Type
7752208 Inorganica Chimica Acta 2012 14 Pages PDF
Abstract
► The expeditious synthesis of novel cyanovinylidene complexes is described. ► The complexes have been crystallographically and (spectro)electrochemically characterised. ► DFT studies demonstrate a Cα-localised LUMO, consistent with experimental results. ► Improvements to the preparative routes of FeCl(dppe)Cp and 1-cyano-4-dimethylaminopyridinium tetrafluoroborate are described.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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