Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7752208 | Inorganica Chimica Acta | 2012 | 14 Pages |
Abstract
⺠The expeditious synthesis of novel cyanovinylidene complexes is described. ⺠The complexes have been crystallographically and (spectro)electrochemically characterised. ⺠DFT studies demonstrate a Cα-localised LUMO, consistent with experimental results. ⺠Improvements to the preparative routes of FeCl(dppe)Cp and 1-cyano-4-dimethylaminopyridinium tetrafluoroborate are described.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Ella M. Long, Neil J. Brown, Wing Y. Man, Mark A. Fox, Dmitry S. Yufit, Judith A.K. Howard, Paul J. Low,