Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7752836 | Journal of Fluorine Chemistry | 2015 | 5 Pages |
Abstract
The local structure of molten CsF-AF (AÂ =Â Li, Na, K and Rb) has been studied by high temperature Nuclear Magnetic Resonance (NMR) spectroscopy. The 19F and 133Cs chemical versus the molar fraction of CsF presents an anomaly in the series of the alkaline. The evolutions of 19F and 133Cs chemical shifts versus CsF-AF composition have been interpreted as a signature of dynamical local scale distribution heterogeneities.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Anne-Laure Rollet, Catherine Bessada,