| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7753185 | Journal of Fluorine Chemistry | 2014 | 8 Pages |
Abstract
The Sheppard reaction most likely proceeds through the intermediacy of aryl thiolates whose formation from aromatic disulfides is catalyzed by coinage metal (MÂ =Â Cu, Ag, and Au) surfaces. Aromatic sulfenyl chlorides were prepared from the chlorination of aromatic disulfides, and these substrates offer a new route to pentafluorosulfanybenzenes via their direct fluorination.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Alexey M. Sipyagin, Colin P. Bateman, Andrej V. Matsev, Alfred Waterfeld, Robert E. Jilek, Christopher D. Key, Gregory J. Szulczewski, Joseph S. Thrasher,