Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7753338 | Journal of Fluorine Chemistry | 2013 | 7 Pages |
Abstract
- The reactions between carbonyls and PhSO2CF2H have been accomplished using in situ generated substoichiometric amount of base.
- A protocol for effective difluoro(phenylsulfonyl)methylation of enolizable aldehydes under basic conditions is developed.
- The reactivity difference between PhSO2CF2H and CF3H toward carbonyls has been disclosed and rationalized.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Mingyou Hu, Bing Gao, Chuanfa Ni, Laijun Zhang, Jinbo Hu,