Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7753495 | Journal of Fluorine Chemistry | 2013 | 6 Pages |
Abstract
⺠Synthesis of β-trifluoromethylated ketones from allylic alcohols by an isomerization reaction. ⺠Detailed study of the reaction parameters and mechanistic insights clearly indicate a strong fluorine effect. ⺠High level of enantiospecificity was demonstrated in the reaction whereas poor enantioselectivity was achieved so far.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Vincent Bizet, Xavier Pannecoucke, Jean-Luc Renaud, Dominique Cahard,