| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7754905 | Journal of Inorganic Biochemistry | 2015 | 46 Pages |
Abstract
Stoichiometry and stability of RhCp* (Cp*, pentamethylcyclopentadienyl) complexes of 2,2ʹ-bipyridine and ethylenediamine were characterized in aqueous solution and compared with (O,O) donor deferiprone complexes. Interaction of these organorhodium compounds with human serum albumin was characterized by 1H NMR, ultrafiltration and fluorometry involving site markers and amino acid side chain models.
Keywords
PBSDHPHMMLMMPTAN-acetyl-l-methioninePICHSADSSλemλexbpyPentamethylcyclopentadienylDeferiprone1-Methylimidazole1,10-Phenanthroline4,4-dimethyl-4-silapentane-1-sulfonic acidCp*UV-visibleUV–VisAlbuminhuman serum albuminEthylenediaminehigh molecular masslow molecular massrhodiumX-ray crystal structurePhosphate buffered salinePhenMaltolHalf-sandwich complexesWarfarinStability constantsPolypyridyl
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Ãva A. Enyedy, János P. Mészáros, Orsolya Dömötör, Carmen M. Hackl, Alexander Roller, Bernhard K. Keppler, Wolfgang Kandioller,