| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7755343 | Journal of Inorganic Biochemistry | 2013 | 8 Pages |
Abstract
Ferric/ferrous tris(hydroxymethyl)phosphine (THMP)-H93G myoglobin (Mb) complexes having THMP/X (X = none, THMP, imidazole, CO and O2) heme axial ligand(s) have been prepared and examined here with UV-visible and magnetic circular dichroism (MCD) spectroscopy. Interestingly, THMP/CO- (shown here, a hyperporphyrin) and bis-THMP-bound ferrous H93G Mb exhibited P450-type UV-Vis and MCD spectra.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Shengfang Sun, Masanori Sono, John H. Dawson,