Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7755673 | Journal of Organometallic Chemistry | 2018 | 9 Pages |
Abstract
A series of new 6-substituted 3,5-di-tert-butylcatecholato complexes of triphenylantimony(V) based on 6-alkoxymethyl-3,5-di-tert-butylcatechols and o-benzoquinones (where alkoxy group is methoxy, ethoxy, isopropoxy, tert-butoxy, n-hexoxy functions) have been synthesized. Novel redox active catechol, o-benzoquinone ligands and triphenylantimony(V) catecholates have been characterized in details. The molecular structures of mono- and binuclear triphenylantimony(V) catecholates in crystal were determined using single-crystal X-ray analysis. The electrochemical behaviour of complexes and influence of alkoxy methyl group were studied by cyclic voltammetry.168
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Authors
Andrey I. Poddel'sky, Tatyana V. Astaf'eva, Ivan V. Smolyaninov, Maxim A. Arsenyev, Georgy K. Fukin, Nadezhda T. Berberova, Vladimir K. Cherkasov, Gleb A. Abakumov,