Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7755915 | Journal of Organometallic Chemistry | 2018 | 6 Pages |
Abstract
Piano-stool Mn(I) cationic carbyne complexes react with bis(diphenylphosphino)methane to afford selectively either cyclic λ5-1,3-diphosphetium semi-ylides or Mn(I) complexes featuring unprecedented phosphonioketene ligands, depending on the nature of the carbyne substituent, aryl or alkyl, respectively.135
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Dmitry A. Valyaev, Kamil I. Utegenov, Vassily V. Krivykh, Jérémy Willot, Nikolai A. Ustynyuk, Noël Lugan,