| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7755963 | Journal of Organometallic Chemistry | 2018 | 17 Pages |
Abstract
Magnetic spin transfer NMR was used to investigate phosphine exchange reactions in complexes of the type [Rh(N,O-Bid)(CO)(PPh3)]. The rate of exchange in [Rh(2,6-Cl2-Phony)(CO)(PPh3)] is approximately three times faster than the methylated counterpart; the methyl substituents increase the electron density of the d-orbitals of the rhodium atom and stabilize the intermediate.156
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Gertruida J.S. Venter,