Article ID Journal Published Year Pages File Type
7756416 Journal of Organometallic Chemistry 2017 68 Pages PDF
Abstract
NMR chemical shifts of (Left) single-bonded complexes and (Right) double-bonded complexes. NMR chemical shifts of d0, first-, second- and third-row transition metal compounds show two unique trends for single-bonded and multiple-bonded ligands, respectively. Scandide (d-block) and lanthanide (f-block) contractions and relativistic effects are believed to contribute to the NMR shifts, leading to the observed trends.173
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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