| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7756587 | Journal of Organometallic Chemistry | 2015 | 31 Pages |
Abstract
The unsaturated cluster [Os3(μ-H)2(CO)10] reacts with a variety of Ï-conjugated phosphole ligands to give mono-substituted derivatives with fluxional behavior, while the reaction of [Os3(CO)10(CH3CN)2] with cyanoethyldiphenylphosphine affords mono- and bis(phosphine)-substituted clusters, whose dynamic behavior is studied by variable-temperature 1H and 31P NMR spectroscopy.
Keywords
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yomaira Otero, Deisy Peña, Alejandro Arce, Muriel Hissler, Regis Réau, Ysaura De Sanctis, Edgar Ocando-Mavárez, Rubén Machado, Teresa González,