| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7756635 | Journal of Organometallic Chemistry | 2015 | 6 Pages |
Abstract
Four new unsolvated lanthanide bis(alkynylamidinato) amide complexes [c-C3H5-CC-C(NR)2]2LnN(SiMe3)2 (2: Ln = Ce, R = iPr; 3: Ln = Ce, R = Cy; 4: Ln = Nd, R = Cy; 5: Ln = Ho, R = Cy) have been prepared and structurally characterized through single-crystal X-ray diffraction. An initial catalytic study showed that the new complexes cannot be reliably employed as precatalysts for hydroamination/cyclization reactions.
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Authors
Farid M. Sroor, Cristian G. Hrib, Liane Hilfert, Larissa Hartenstein, Peter W. Roesky, Frank T. Edelmann,