Article ID Journal Published Year Pages File Type
7756654 Journal of Organometallic Chemistry 2015 16 Pages PDF
Abstract
Air-stable phosphite ligands were synthesized without added external base. Organoplatinum(II) complexes of the air-stable bulky phosphite ligands have been synthesized and characterized. These compounds are very robust and can be stored on the bench without decomposition. Upon thermolysis at 100 °C, these complexes cyclometallate via intramolecular sp3 C-H activation.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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