Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7756654 | Journal of Organometallic Chemistry | 2015 | 16 Pages |
Abstract
Air-stable phosphite ligands were synthesized without added external base. Organoplatinum(II) complexes of the air-stable bulky phosphite ligands have been synthesized and characterized. These compounds are very robust and can be stored on the bench without decomposition. Upon thermolysis at 100 °C, these complexes cyclometallate via intramolecular sp3 C-H activation.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Kyle A. Grice, Jason A. Kositarut, Anthony E. Lawando, Roger D. Sommer,