Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7756698 | Journal of Organometallic Chemistry | 2015 | 12 Pages |
Abstract
A series of half-sandwich ruthenium(II) complexes of the type [Ru(η6-C6H6)(Nâ©C)L]PF6 bearing cyclometalated N,N-dimethylbenzylamine and 2-phenylpyridine moieties has been prepared. The compounds were tested in ATRP of styrene and vinyl acetate. The activity is strongly dependent on the nature of the ligands and the mechanism revealed to be quite complex.
Keywords
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Vanessa MartÃnez Cornejo, Jessica Olvera Mancilla, Salvador López Morales, José Alberto Oviedo Fortino, Simón Hernández-Ortega, Larissa Alexandrova, Ronan Le Lagadec,