| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7756832 | Journal of Organometallic Chemistry | 2015 | 23 Pages |
Abstract
Conjugate additions to alkoxycarbene cations of the iron chiral auxiliary [(η5-C5H5)Fe(CO)(PPh3)C(OMe)CHCHR]+ proceed with high diastereoselectivity. Subsequent protonation and demethylation gives iron acyl complexes of opposite relative configuration to those which result from conjugate addition of the same nucleophile to the corresponding α,β-unsaturated iron acyl complex.235
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Diastereoselective conjugate additions to alkoxycarbene cations of the iron chiral auxiliary [(η5-C5H5)Fe(CO)(PPh3)C(OMe)CHCHR]+](/preview/png/7756832.png "First Page Preview: Diastereoselective conjugate additions to alkoxycarbene cations of the iron chiral auxiliary [(η5-C5H5)Fe(CO)(PPh3)C(OMe)CHCHR]+")
Authors
Stephen G. Davies, Robert J.C. Easton, Jeffrey M. McKenna, Mario E.C. Polywka, James E. Thomson,