Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7756865 | Journal of Organometallic Chemistry | 2015 | 20 Pages |
Abstract
Post-synthetic Suzuki coupling reactions have been undertaken on the halide-functionalised metal-organic frameworks (MOFs) [Zn4O(bdc-Br)3] (bdc-Br = 2-bromo-1,4-benzenedicarboxylate, IRMOF-2) and [Zn4O(bdc-I)3] (bdc-I = 2-iodo-1,4-benzenedicarboxylate). Although the bulky catalyst employed leads to relatively low conversions, the use of core-shell MOFs demonstrates that the reactions are not confined to the crystal surfaces.112
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Andrew D. Burrows, Laura C. Fisher, Timothy J. Mays, Sean P. Rigby, Sharon E. Ashbrook, Daniel M. Dawson,