Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7756889 | Journal of Organometallic Chemistry | 2015 | 12 Pages |
Abstract
Heterodinuclear hydridoplatinum and -palladium complexes, Lâ²2HPt(or Pd)MLn were synthesized by the oxidative addition of corresponding mononuclear hydride complex with zero-valent platinum and palladium complexes. Facile exchanging process between H and M in (dppe)HPt(or Pd)MLnis observed. Reversible hydride migration from Pt(or Pd) to M was enhanced by electron deficient alkenes.117
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Nobuyuki Komine, Ayako Kuramoto, Toshiyuki Yasuda, Tatsuya Kawabata, Masafumi Hirano, Sanshiro Komiya,