Article ID Journal Published Year Pages File Type
7756895 Journal of Organometallic Chemistry 2015 9 Pages PDF
Abstract
Complexes 1-4 were synthesized. Despite its rigid backbone and trans-oriented phosphino groups, the 1,2-bis(diphenylphosphino)ethylene ligand adopts a syn conformation with nearly eclipsed P-Re bonds in these complexes. Complex 2 forms dimers in the solid state via S⋯S interactions. The nature of bonding of these interactions was investigated theoretically.201
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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