Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7757077 | Journal of Organometallic Chemistry | 2014 | 6 Pages |
Abstract
The syntheses of organohydridosilanes containing Y,C,Y-chelating ligands of the general formula PhL1-3SiH2 (1, L1Â =Â C6H3(CH2OtBu)2-2,6; 2, L2Â =Â C6H3(CH2OtBu)-2-(CH2NMe2)-6; 3, L3Â =Â C6H3(CH2NMe2)2-2,6) are reported. While PhL1SiH2 (1) is crystalline and molecular structure was determined by X-ray diffraction, the vapour pressures of oily compounds 2 and 3 were determined as well. In addition, the effect of the donor atoms upon the reactivity of organohydridosilanes 1-3 was studied further.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Miroslav Novák, Libor Dostál, Zdenka PadÄlková, Klaus Jurkschat, Christina Dietz, KvÄtoslav RůžiÄka, Michal Fulem, AntonÃn LyÄka, Roman Jambor,