Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7757139 | Journal of Organometallic Chemistry | 2014 | 6 Pages |
Abstract
The quantity of the cis isomer of [Cr(cyclam)(CCR)2]OTf obtained in syntheses starting from cis-[Cr(cyclam)(OTf)2]OTf depends on the extent of isomerization and can be controlled by choice of solvent. Syntheses of the previously unreported cis-[M(cyclam)(CCCF3)2]OTf (MÂ =Â Cr3+ and Rh3+) have been developed and the photophysics of these complexes is reported.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Parth U. Thakker, Chivin Sun, Levan Khulordava, Colin D. McMillen, Paul S. Wagenknecht,