| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7757139 | Journal of Organometallic Chemistry | 2014 | 6 Pages |
Abstract
The quantity of the cis isomer of [Cr(cyclam)(CCR)2]OTf obtained in syntheses starting from cis-[Cr(cyclam)(OTf)2]OTf depends on the extent of isomerization and can be controlled by choice of solvent. Syntheses of the previously unreported cis-[M(cyclam)(CCCF3)2]OTf (MÂ =Â Cr3+ and Rh3+) have been developed and the photophysics of these complexes is reported.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Synthetic control of the cis/trans geometry of [M(cyclam)(CCR)2]OTf complexes and photophysics of cis-[Cr(cyclam)(CCCF3)2]OTf and cis-[Rh(cyclam)(CCCF3)2]OTf](/preview/png/7757139.png "First Page Preview: Synthetic control of the cis/trans geometry of [M(cyclam)(CCR)2]OTf complexes and photophysics of cis-[Cr(cyclam)(CCCF3)2]OTf and cis-[Rh(cyclam)(CCCF3)2]OTf")
Authors
Parth U. Thakker, Chivin Sun, Levan Khulordava, Colin D. McMillen, Paul S. Wagenknecht,