| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7757263 | Journal of Organometallic Chemistry | 2014 | 32 Pages |
Abstract
The cyclometallation of allylbenzenes (Ar= Ph, 4-MeO-Ph, 3,4-(MeO)2-Ph) with EtAlCl2 (Et2AlCl) and Mg in the presence of Zr and Ti catalysts (Dzhemilev reaction) has been studied. The reaction runs with high diastereoselectivity and provides 2R(S), 3R(S)-dibenzyl butanes with yield of 48-69%.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Lyudmila V. Parfenova, Tatyana V. Berestova, Pavel V. Kovyazin, Aydar R. Yakupov, Ekaterina S. Mesheryakova, Leonard M. Khalilov, Usein M. Dzhemilev,