Article ID Journal Published Year Pages File Type
7757292 Journal of Organometallic Chemistry 2014 4 Pages PDF
Abstract
Microwave heating is used to rapidly synthesize the osmium(I) carbonyl complexes Os2(μ-sebacate)(CO)6 and [Os2(CO)6]2(μ4-1,3-adamantanediacetate)2 from Os3(CO)12 in a single step. In the diosmium complex, the dicarboxylato ligand forms an intramolecular chelate ring. In the tetraosmium complex, two dicarboxylato ligands form intermolecular bridges between two Os2 units.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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