| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7757301 | Journal of Organometallic Chemistry | 2014 | 10 Pages |
Abstract
DFT studies of alkynol polymerization by Grubbs-type and Hoveyda-Grubbs catalysts indicate that the α-insertion path is kinetically preferred over β-insertion. Besides typical linear products that can immediately undergo the next insertion step, cyclic products can be also formed, by oxygen-chelation to the ruthenium centre or as less stable rutenacyclobutene species.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
PaweÅ Åliwa, JarosÅaw Handzlik, Izabela CzeluÅniak,