| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7757331 | Journal of Organometallic Chemistry | 2014 | 28 Pages |
Abstract
The catalytic system formed in situ from trans-[PdBr2(PPh3)2]/Base/PPh3/LiBr is highly active and selective in the oxidative carbonylation of iPrOH to the corresponding oxalate using benzoquinone as a stoichiometric oxidant. The influence of each component in the catalytic system is discussed. A catalytic cycle is proposed.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
E. Amadio, L. Toniolo,