| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7757375 | Journal of Organometallic Chemistry | 2014 | 50 Pages |
Abstract
The pseudomonomolecular (THF-catalyzed) rate constants kÏ of cis/trans interconversion of the trisolvated, monomeric ground-states CIP and CIP' in THF via solvent-separated ion pairs (SSIP) can be measured through line shape analyses of the pairwise “coalescing” (averaging) NMR signals of diastereotopic 1H and 13C nuclei at positions 1/3 and 4/5.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Rudolf Knorr, Karsten-Olaf Hennig, Petra Böhrer, Bernhard Schubert,