Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7757420 | Journal of Organometallic Chemistry | 2013 | 9 Pages |
Abstract
The [3 + 2] cycloaddition products Mo(η3-C3H5)(CO)2(en)(N4CR) (R = C(CN)C(CN)2, C6H4NO2, CHCH2), Mo(η3-C3H5)(CO)2(dppe){N4C(C(CN)C(CN)2), and Mo(η3-C3H5)(CO)2(L2){N3C2(CO2C2H5)2} (L2 = en, dppe), and the isothiocyanato compounds Mo(η3-C3H5)(CO)2(L2)(NCS) were prepared and structurally characterized. These compounds are fluxional in solution and the heterocycle ring is N(2) bound to the metal.
Related Topics
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Authors
Fu-Chen Liu, Jie-Er Liang, Jie-Yu Jin, Yu-Liang Lin, Yong-Jui Chu, Pei-Shan Yang, Gene-Hsian Lee, Shie-Ming Peng,