| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7757425 | Journal of Organometallic Chemistry | 2013 | 5 Pages |
Abstract
The rhodium(III) cationic methyl acetamidine complex, trans-[Rh(Acac)(PPh3)2(CH3){NHC(NH2)CH3}][BPh4], is formed by ammination of coordinated acetonitrile in trans-[Rh(Acac)(PPh3)2(CH3)(CH3CN)][BPh4]. Z-configuration of the acetamidine ligand is stabilized by hydrogen bonding with the oxygen atom of the acetylacetonate ligand.
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Synthesis and characterization of acetamidine rhodium(III) cationic methyl complex, trans-[Rh(Acac)(PPh3)2(CH3){NHC(NH2)CH3}][BPh4], produced by ammination of acetonitrile ligand in trans-[Rh(Acac)(PPh3)2(CH3)(CH3CN)][BPh4]](/preview/png/7757425.png "First Page Preview: Synthesis and characterization of acetamidine rhodium(III) cationic methyl complex, trans-[Rh(Acac)(PPh3)2(CH3){NHC(NH2)CH3}][BPh4], produced by ammination of acetonitrile ligand in trans-[Rh(Acac)(PPh3)2(CH3)(CH3CN)][BPh4]")
Authors
Elizaveta P. Shestakova, Yuri S. Varshavsky, Victor N. Khrustalev, Sergei N. Smirnov,