| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7757468 | Journal of Organometallic Chemistry | 2012 | 5 Pages |
Abstract
⺠1-Isothiocyanato-3,7,10-trimethyl-2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3.0]undecanes has been synthesized. ⺠The synthesized compound is very reactive due to presence of exocyclic -NCS moiety. ⺠The difference between the dative and covalent Si-N bond distance (0.229 Ã
) is minimal. ⺠X-ray crystal structure reveals that the molecule adopts trigonal bipyramidal geometry. ⺠The asymmetric unit contains two crystallographically independent molecules.
Related Topics
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Authors
Gurjaspreet Singh, Amandeep Saroa, Mridula Garg, Raj Pal Sharma, A.I. Gubanov, A.I. Smolentsev,