Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7757490 | Journal of Organometallic Chemistry | 2012 | 6 Pages |
Abstract
⺠Hydrogenolysis of a series of model Ziegler-Natta catalysts was studied within DFT. ⺠Reactivity of Ti-H bond towards ethylene and propylene insertion was investigated. ⺠Activity depression and increase in ethylene and propylene polymn were explained. ⺠Reactivity of the catalyst towards propylene 1,2- and 2,1- insertion was compared.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Naeimeh Bahri-Laleh, Mehdi Nekoomanesh-Haghighi, Seyed Amin Mirmohammadi,