| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7757722 | Journal of Solid State Chemistry | 2018 | 15 Pages |
Abstract
Three new mercury coordination polymerswere successfully prepared and characterized. Complexes 1 and 2 are isomers resulted from different one dimensional (1D) mercury halides chains, and are 3D supramolecular structures. Complex 3 possesses a 2-fold interpenetrated diamondoid network with intersecting channels. TDDFT calculations reveal the mechanisms of the fluorescence emission and optical absorption spectra indicate 1-3 have wide optical band-gaps and can be probably used as wide optical band-gap semiconductor materials.244
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Dong-Sheng Liu, Yan Sui, Guang-Ming Ye, Hui-ying Wang, Jian-Qi Liu, Wen-Tong Chen,