| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7757815 | Journal of Solid State Chemistry | 2018 | 7 Pages |
Abstract
Using Ca metal as the reducing agent, a series of reduced vanadium silicates CaxLn1âxVSiO5 (Ln = Ce-Nd, Sm-Lu, Y) was synthesized utilizing BaCl2/NaCl flux. The 3D structure, which belongs to the tilasite (CaMgAsO4F) structure type consists of 1D VO6 octahedra, SiO4 groups, and (Ca/Ln)O7 polyhedra. The magnetic susceptibility data of the series support the existence of antiferromagnetic behavior at low temperatures.258
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Dileka Abeysinghe, Mark D. Smith, Gregory Morrison, Jeongho Yeon, Hans-Conrad zur Loye,