Article ID Journal Published Year Pages File Type
7760987 Journal of Solid State Chemistry 2012 11 Pages PDF
Abstract
► Crystallographic properties of Ba8GaxSi46−x clathrates are characterized. ► Arc melting and spark plasma sintering process enables increase of Ga content. ► We elucidate the Ga composition dependence of thermoelectric properties. ► Thermoelectric figure of merit ZT is improved due to the increased Ga content. ► Calculation predicts a potential ZT=0.8 at 900 K at optimized carrier concentration.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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