| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7761211 | Journal of Solid State Chemistry | 2012 | 7 Pages |
Abstract
⺠Experiments confirm theory prediction of a solid solution in Co3O4-Co2ZnO4 spinels. ⺠Thermodynamics of mixing studied by calorimetric, electrical, structural methods. ⺠Cation distributions found to be mostly normal for various compositions. ⺠Mixing enthalpy is larger than prediction and inconsistent with strain effects. ⺠Changes in Co3+ spin state proposed as source of large mixing enthalpy/entropy.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Nicola H. Perry, Thomas O. Mason, Chengcheng Ma, Alexandra Navrotsky, Yezhou Shi, Joanna S. Bettinger, Michael F. Toney, Tula R. Paudel, Stephan Lany, Alex Zunger,