Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7767188 | Tetrahedron: Asymmetry | 2014 | 11 Pages |
Abstract
A range of known and novel N-phosphoryl oxazolidinones and imidazolidinones were prepared and screened in the kinetic resolution of a range of racemic magnesium chloroalkoxides. Models are proposed to account for the enantioselectivity achieved based on a combination of chiral relay effects, generation of transient stereochemistry and the structure of the intermediate magnesium alkoxide.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Samuel Crook, Nigel J. Parr, Jonathan Simmons, Simon Jones,