| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7769845 | Biochemical Systematics and Ecology | 2012 | 8 Pages |
Abstract
⺠New minor 4,4,14-trimethylsterol glycoside with unprecedented hydroxyl group at C-18 has been isolated from Eupentacta fraudatrix. ⺠Its structure allows to clarify some peculiarities of glycoside biosynthesis. ⺠Aglycone moiety biosynthesis does not precede glycosylation, but is concurrent. ⺠9β-H configuration and type of unsaturation are formed in early biosynthetic stages.
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Organic Chemistry
Authors
Alexandra S. Silchenko, Anatoly I. Kalinovsky, Sergey A. Avilov, Pelageya V. Andryjashchenko, Pavel S. Dmitrenok, Vladimir I. Kalinin, Valentin A. Stonik,