Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7790110 | Carbohydrate Polymers | 2015 | 5 Pages |
Abstract
The conversion of cellulosic biomass directly into valuable chemicals becomes a hot subject. Six novel acidic ionic liquids (ILs) based on 2-phenyl-2-imidazoline were synthesized and characterized by UV-VIS, TGA, and NMR. The novel acidic ionic liquids were investigated as catalysts for the hydrolysis of cellulose in 1-butyl-3-methylimidazolium chloride ([Bmim]Cl). The acidic ionic liquids with anions HSO4â and Clâ showed better catalytic performance for the hydrolysis of cellulose than those with H2PO4â. The temperature and dosage of water affect significantly the yield of total reducing sugar (TRS). When the hydrolysis of cellulose was catalyzed by 1-propyl sulfonic acid-2-phenyl imidazoline hydrogensulfate (IL-1) and the dosage of water was 0.2 g, the TRS yield was up to 85.1% within 60 min at 100 °C. These new acidic ionic liquids catalysts are expected to have a wide application in the conversion of cellulose into valuable chemicals.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Kelei Zhuo, Quanzhou Du, Guangyue Bai, Congyue Wang, Yujuan Chen, Jianji Wang,