| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7794062 | Carbohydrate Research | 2015 | 17 Pages |
Abstract
- The effect of an extra EWG in DA reactions of a sugar dienophile was studied.
- Conceptual DFT calculations predicted an important enhancement in the reactivity.
- This treatment failed in predicting the regiochemical preference with some dienes.
- MPW1K/6-31G* calculations correctly reproduced the experimental observations.
- The ease of pyramidalization dictates the regioselectivity.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Germán F. Giri, Ariel M. Sarotti, Rolando A. Spanevello,