Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7794628 | Carbohydrate Research | 2013 | 8 Pages |
Abstract
- Conjugate addition patterns on newer sugar vinyl sulfoxides are reported.
- Sugar vinyl sulfoxides undergo conjugate addition reactions diastereoselectively.
- The nature of nucleophile and substituent at the sulfinyl sulfur are important.
- Primary amines, carbon and sulfur nucleophiles prefer axial addition pattern.
- Whereas secondary amine nucleophiles prefer equatorial addition pattern.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Arunima Mukherjee, Narayanaswamy Jayaraman,