Article ID Journal Published Year Pages File Type
7794628 Carbohydrate Research 2013 8 Pages PDF
Abstract

- Conjugate addition patterns on newer sugar vinyl sulfoxides are reported.
- Sugar vinyl sulfoxides undergo conjugate addition reactions diastereoselectively.
- The nature of nucleophile and substituent at the sulfinyl sulfur are important.
- Primary amines, carbon and sulfur nucleophiles prefer axial addition pattern.
- Whereas secondary amine nucleophiles prefer equatorial addition pattern.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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