| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 77997 | Solar Energy Materials and Solar Cells | 2014 | 8 Pages |
•Cu2ZnSnS4 thin films were deposited by co-sputtering quaternary alloy, and ZnS targets.•Nanorods were used in the production of devices with a favorable efficiency of approximately 6%.•One-step sputtering shows great potential for mass production of thin film Cu2ZnSnS4 cells.
Copper zinc tin sulfide (Cu2ZnSnS4, CZTS) is highly abundant in nature. It is an important absorber material for the development of low-cost and sustainable next-generation I2–II–IV–VI4 thin-film solar cells because it has a the tunable direct band gap energy, inexpensive constituent elements, and a large absorption coefficient in the visible wavelength region. This work develops an efficient one-step vacuum-based approach to depositing CZTS films without the need to supply excess sulfur during/after deposition or to perform any post-sulfurization treatment. This one-step RF sputtering process produces CZTS films that are crystalline, phase-pure, dense, smooth, and continuous. Air Mass 1.5 G power conversion efficiencies of as high as 6% have been achieved with an antireflection coating, demonstrating that this new approach has great potential as a low-cost alternative for high-efficiency CZTS solar cell production.
